Cool Stuff > Crystallization K - 12 and Other Stuff > Copper Sulfate Crystals - Homemade Geodes
Copper Sulfate Crystals - Homemade Geodes  
Safety: Warning! Copper sulfate is an irritant. Harmful if swallowed. If swallowed, give water and call a physician. In case of contact with eyes or skin, flush with water. For eyes, get medical attention. Keep out of the reach of children. Be sure to rinse any solutions down the drain with lots and lots of water. After you are finished with your Homemade Geode, wrap it in plastic and place it in a covered trash can.

About the Experiment
This experiment allows one to grow crystals of copper sulfate by way of temperature. Copper sulfate is more soluble in warm water than cool water.

First, one dissolves an excess amount of copper sulfate in water. What we mean by "an excess amount" is that one adds copper sulfate with gentle stirring to the warm water until no additional copper sulfate solid can be dissolved into the solution. This creates a solution that chemists and the Village People call "saturated." The solution is allowed to cool. As it turns out, one can add more copper sulfate to a warm solution than a cool solution. So what happens when the solution cools? The copper sulfate cannot stay in the solution. Instead it forms crystals. So in this experiment, one initially grows crystals by using a Temperature Method. If the experiment sits for more than a day, then some water will evaporate from the solution. The copper sulfate cannot evaporate and stays behind. As more water evaporates, there is less room for the copper sulfate to hang out in the water (think crowded room). So to make the best use of the space, the copper sulfate molecules gets together with one another in a very organized way. Think of chairs lined up in rows in an auditorium, or cars parked in a large parking lot, or best yet, cars parked in a multiple story parking lot. The crystals grow larger as more and more copper sulfate molecules (cars) pile onto the crystal (parking garage full of cars).

Geodes? Mother nature's parking lot for minerals. Geodes are rocks, where lots of minerals and water passed through and into the rock. After millions of years the water moves on (evaporates) leaving the minerals behind, and voile! Crystals! So your eggshell containing copper sulfate crystals is a quickie geode.

Protocol

1. Obtain a clean eggshell. In other words, carefully crack open a chicken egg, discard the egg and keep the eggshell. Since we are using the eggshell to hold the solution, try to open the egg without making to many cracks in the shell (create two halves for examples, or try to take off just the end of the shell for a different effect). Clean the egg from the shell.

2. To 1/4 cup of hot water in a separate container (not the eggshell yet), add some copper sulfate. Stir. Add copper sulfate and stir until no more copper sulfate can be dissolved in the hot water. For the best crystals do not add way too much copper sulfate. Add just enough so that only a small amount (a few pinches) of solid material cannot be dissolved into solution.

3. Pour the copper sulfate solution into the eggshell(s).

4. Place the eggshell(s) in an area where they will not be moved, spilled or disturbed for at least two to three days. Avoid placing the shells containing the solution where someone might eat, break or spill the experiment. Be sure to place the eggshell in or on something to protect what ever sits underneath (a table or counter for example) in case the eggshell(s) leaks.

5. Observe the solution in the shell each day. Crystals should appear after the first day and will be looking most excellent by day two and three.

6. For a better view of the crystals, remove and discard the solution after a few days or a week or two. Allow the crystals to dry in the eggshell. Cool eh?

Point to Ponder

What would happen if we added a lot of water to the homemade geode or placed the homemade geode in a container with a lot of water? Do you think the crystals would remain, or would they dissolve? Why?
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